The structural properties of cobalt catalysts and their active component are studied. The influence of metal oxides on the specific surface area, pore volume and size, the average crystallite size and the active surface area of the catalyst Co-Al2O3/SiO2 was studied.
Keywords: Fischer-Tropsch synthesis, synthetic hydrocarbons, catalyst, cobalt, promoter, carrier, specific surface, porous structure, catalytic activity, degree of reduction, active surface area
The physical and chemical properties of cobalt catalysts promoted by manganese oxides for the synthesis of hydrocarbons by the Fischer-Tropsch method are studied. The influence of polymorphic modifications of the alumina carrier on the specific surface area, pore volume, degree of reduction, size of cobalt crystallites,catalytic activity, dispersion degree of catalyst reduction is considered.
Keywords: Synthesis of Fischer-Tropsch, synthetic hydrocarbons, the cobalt catalyst, promoter MnO2, the carrier of Al2O3, specific surface area, the degree of recovery of the catalytic activity, dispersion, and the crystallites of cobalt
The article presents an analysis of promising research on the formation of vibrational mechanochemical coatings from the point of view of practical use in the real sector of the economy
Keywords: combined methods of treatment, vibration treatment, the vibration mechano-chemical (chemical-mechanical) coverage webrevolve technological system, mechanical coating, fragmentary nature, plastic deformation, uniform coating, vibrowave impact, microstructu
Article is devoted problems of safety of traffic. In given article are sounded a number of the reasons of occurrence of failures on highways. In article questions of influence of psychophysiological features of drivers on occurrence accidents are considered. The special attention is given that use of cellular telephones by drivers (despite prohibition by traffic regulations), and also every possible advertising materials in sight of drivers do not promote concentration of attention on driving process. Also in article questions of increase of safety of pedestrians, as participants of traffic are mentioned. In article the interrelation between road conditions and safety of traffic is investigated. That fact is marked, the reasons of adverse influence of road conditions can be obvious and hidden. In article the developed practice of roads design is analyzed. The given practice, in a due measure, does not consider requirements of landscape designing. Which, in turn, though are registered in the arch of rules, but have recommendatory character. Also in article questions of use of the minimum parameters of highways are mentioned at its designing.
Keywords: Safety of traffic, accidents , a highway, the driver, the pedestrian, roads design, a road condition, road conditions, intensity of movement, the road maintenance, landscape design of road
In the article the features of application of logistic approaches of the organization of movement of the cable cars, as well as the method of selecting the cable car and the slopes at various characteristics of the operation of the complex. The results of experimental research on the network of cable cars of the mountain resort "Rosa Khutor"are offered. The paper uses the methods of monitoring the movement of passengers on cable cars by means of identification by ski pass and GPS
Keywords: transport mobility, route network, public transport, automated monitoring of passenger traffic, logistics approach, cable car, monitoring of cable car congestion on-line, traffic volume, digital transport management system
The problem of calculating rods for vector perturbations consisting of five components is solved: 1. kinematic transverse vibrations of the left end; 2. kinematic transverse vibrations of the right end; 3. dynamic bending moment at the left end; 4. dynamic bending moment at the right end; 5 dynamic uniformly distributed lateral load along the length of the rod. The transfer functions from each disturbance are obtained separately. Using these functions, we obtained the elements of the spectral matrix for stationary random processes, taking into account their correlation. The most common types of processes are considered: exponentially correlated random process; process with latent periodicity (with characteristic frequency); truncated white noise. The formula for obtaining the dispersion of displacement of sections is shown.
Keywords: rod, harmonic oscillations, natural frequency, kinematic disturbances, dynamic disturbances, transfer function, correlation matrix, random process, delta-correlated random process, latent periodicity, truncated white noise
The model of the occurrence of failures as a result of aging of insulation materials of power cable lines is considered. It is shown that the residual life depends on the ratio of the safety margin and the ultimate strength of the materials used. A simulation of the resource actuation processes was carried out using a mathematical model of the insulation state that relates the time and probability of its trouble-free operation with certain parameters of it. The model allows to predict the state of the insulation and the service life of the power cable lines.
Keywords: Reliability, life, insulation materials, heat aging
The paper considers an optical laser-free system for express analysis of vibration state, which includes a dedicated backlight and a videocamera of vision system, which is a displacement sensor. The problem of determining the degree of mutual influence of the reflecting properties of the surface and the spectral composition of the radiation of the light source on the noise level of the CCD matrix is solved. Using dispersion analysis of the results of a field experiment, it was determined that the spectral composition of the backlight is the most significant factor; the best combinations of parameters were identified. Comparison of the noise level with the real vibration signal showed the crucial role of the selection of combinations of the backlight and the type of the reflecting surface.
Keywords: noise CCD, dispersion analysis, vision system, vibration control, optical measurement, reflective properties, spectral composition, backlight, vibration
The article investigates the process of organization of the public passenger urban transport of the city of Rostov-on-don and regularities of the process of organization of the public passenger urban transport of the city of Rostov-on-don, the relationship of the factors influencing this process.
Keywords: preferential categories of passengers, passenger traffic, transport mobility, route network, public transport, regular passenger traffic, automated monitoring of passenger traffic
The parameters of the porous structure and the active surface of cobalt catalysts for Fischer-Tropsch synthesis (SFT) prepared by the impregnation method have been studied. Characteristics of composition and porous structure were studied using elemental analysis and the Brunauer-Emmett-Taylor method (BET). The effect of the addition of oxide promoters on the specific surface area, pore volume and pore size of the Co / SiO2 catalyst has been studied.
Keywords: Fischer-Tropsch synthesis, heterogeneous catalyst, promoter, carrier, specific surface area, porous structure, selectivity, activity, dipping method
The parameters of the porous structure and the outer surface of cobalt catalysts for the synthesis of Fischer-Tropsch, promoted by magnesium, prepared by the impregnation method according to moisture capacity, were studied. The effect of polymorphic modification (γ, θ, α) of the carrier on the physicochemical properties of the catalyst Co-Mg / Al2O3 was studied.
Keywords: Fischer-Tropsch synthesis, polymorphic modifications of Al2O3, synthetic motor fuel, catalyst, carrier, elemental analysis, BET method, specific surface, porous structure
The article is devoted to the problem of theoretical research and development of perovskite-based solar cells to optimize their design and increase efficiency. The paper presents a numerical simulation of the transfer and accumulation of charge carriers in the planar p – i – n heterostructure of a solar cell. The simulation is based on a stationary physico-topological model based on the diffusion-drift system of semiconductor equations. The efficiency of solar cells for different perovskite film thickness was obtained. It has been established that the maximum efficiency of the optimized design of a solar cell is about 27% with a perovskite film thickness of 500-700 nm and a defect concentration in it of the order of 1012 cm-3.
Keywords: Numerical simulation, solar cell, perovskite, film thickness, defect concentration, current-voltage characteristic
Experimental studies on the formation of nanoscale structures on the surface of gallium arsenide were carried out. To obtain a modified layer on the substrate surface, the method of focused ion beams was used, and the method of plasma-chemical etching was used for the subsequent formation of structures. According to the research results, structures with a width of 90 to 196 nm and a depth of 2 to 9.6 nm were formed. The results of the studies can be applied as structures for the subsequent formation of quantum dots during molecular beam epitaxy.
Keywords: Nanotechnology, focused ion beam, plasma treatment, atomic force microscope, GaAs
The paper describes the implementation of a fiber-optic single-channel vibration sensor built on the basis of two fiber Bragg gratings, a broadband source, a photodetector and a sound card of a computer used as an ADC
Keywords: vibration, fiber optic sensor, fiber Bragg grating, Fourier transform
Monitoring the condition of indoor objects is an important task of building management systems. To solve the problems of monitoring optimal use of wireless sensors. The purpose of the article is to consider wireless passive sensors that do not require a separate power source. A generalized block diagram of a system for monitoring the condition of objects inside the premises is presented. Two types of sensor data are given: on the basis of radio private identification and on the basis of surface acoustic waves. Their principle of action is revealed and the areas of application in smart home control systems are shown. It is revealed that modern technologies allow solving the problem of providing power to wireless sensors using an external electromagnetic signal.
Keywords: wireless passive sensor, RFID tag, temperature measurement, sensor based on surface acoustic waves