The effect of a zeolite support on the physicochemical properties of cobalt catalysts prepared by the precipitation method and calcined at 400°C was studied. The values of the specific surface of the catalysts, the degree of cobalt reduction, and the dispersion of the metal were determined, and the presence of functional groups on the surface of the catalysts was determined by BET, TPV, TPD-H2, and IR spectroscopy.

Keywords: catalyst, cobalt oxide, hydrocarbons, dispersion, active surface

The effect of a zeolite support on the physicochemical properties of cobalt catalysts was studied on a series of samples with zeolites ZSM-5, HY, and NaX. The catalysts were obtained by precipitation followed by mixing the precipitate with a zeolite support. Their properties were characterized by BET, TPR, TPD-H2, IR spectroscopy. The results of the analysis show that the type of zeolite support affects the specific surface area, reduction of deposited cobalt, and the structural properties of the active component of catalytic systems.

Keywords: precipitated catalyst, cobalt, zeolite, dispersion, specific surface area, active component, synthetic fuel, degree of reduction

The physicochemical properties of cobalt catalysts on a NaX zeolite support have been studied. The parameters of the specific surface area, reduction of deposited cobalt, and structural properties of the active component of catalytic systems have been determined. To establish these properties, the methods of BET, TPR, TPD-H2, IR spectroscopy were used. It is shown that the preparation procedure has a significant effect on the physicochemical characteristics of the samples.

Keywords: catalysts, cobalt, zeolite, dispersion, specific surface area of the active component

The article investigates the role of the preparation method and heat treatment in the formation of the physicochemical properties of cobalt catalysts on ZSM-5 support. Determination of the main characteristics of the samples showed that the Co/ZSM-5 I catalyst obtained by the impregnation method has the optimal cobalt dispersion and crystallite size.

Keywords: synthesis of hydrocarbons, cobalt, zeolite, preparation of catalysts, heat treatment

The results of studies of the structural and chemical properties of cobalt catalysts on zeolite HY support are presented. The samples were characterized by BET, TPR, TPD-H2, and IR-spectroscopy. It was found that these properties largely depend on the preparation method.

Keywords: Fischer-Tropsch synthesis, active surface, cobalt, zeolite, preparation method

The article presents the results of studying the effect of the loading of active metal on the physicochemical properties of cobalt catalysts for the Fischer-Tropsch synthesis on a silicate support, promoted with aluminum. Using the BET, XRF, TPR, TPD-H2 methods, it has been established that the optimum cobalt content is 15‒18 wt. %.

Keywords: Fischer-Tropsch synthesis, catalyst, cobalt, active component, loading

The article considers the effect of Al2O3 loading on the physical and chemical properties of cobalt catalysts. The loading of the alumina additive has a significant effect on both the phase and texture properties, as well as on the cobalt reduction process in the composition of the studied samples. It was found that with increasing loading of the additive, the specific surface area of the catalysts decreases, and the cobalt recovery process slows down.

Keywords: Fischer-Tropsch synthesis, catalyst, cobalt, alumina, promoter, temperature programmed reduction

The article presents the results of research on the morphology of cobalt catalysts for Fischer-Tropsch synthesis on a silicate support with promoting additives of aluminum, manganese and chromium using scanning and transmission electron microscopy. The effect of additives on the surface structure and dimensional characteristics of metallic cobalt was determined.

Keywords: morphology, electron microscopy, catalysts, Fischer-Tropsch synthesis, promoters

The article presents the results of research of the physical and chemical properties of cobalt catalysts on a zeolite support. Methods of BET, thermoprogrammed reduction, thermoprogrammed hydrogen desorption and IR-spectroscopy were used for study. The influence of the support nature on the structural (specific surface area, dispersion of metallic cobalt, size of metal crystallites) and chemical (degree of cobalt reduction) properties of catalysts was established.

Keywords: Fischer-Tropsch synthesis, catalysts, zeolite, hydrocarbon synthesis, structural properties

The article presents the results of studies of cobalt catalysts for the synthesis of hydrocarbons on a silicate support with promoting additives of aluminum, manganese and chromium. The influence of additives on the structural (specific surface area, dispersion of metallic cobalt, size of metal crystallites) and chemical (cobalt reduction degree) properties of catalysts was established.

Keywords: cobalt, catalysts, hydrocarbon synthesis, structural properties, promoters

The physical and chemical properties of cobalt catalysts promoted by manganese oxides for the synthesis of hydrocarbons by the Fischer-Tropsch method are studied. The influence of polymorphic modifications of the alumina carrier on the specific surface area, pore volume, degree of reduction, size of cobalt crystallites,catalytic activity, dispersion degree of catalyst reduction is considered.

Keywords: Synthesis of Fischer-Tropsch, synthetic hydrocarbons, the cobalt catalyst, promoter MnO2, the carrier of Al2O3, specific surface area, the degree of recovery of the catalytic activity, dispersion, and the crystallites of cobalt

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