The synthesis of nanocomposite FeNi3/C based on the PAN, FeCl3 · 6H2O and NiCl2 · 6H2O, whereby the first time by the IR heating at 400 ÷ 700 ° C obtained nanocomposite FeNi3/C FeNi3 particle size of 10 to 80 nm are uniformly distributed UM. Using thermodynamic calculations based on the minimization of the Gibbs energy, confirmed the synthesis of nanocomposite FeNi3/C at T=400 ° C reduction of Fe and Ni with H2, produced during the process of carbonization of polyacrylonitrile with infrared heating. Designed as a nano material of the films can be effectively used as a carrier material for a magnetic information recording superdense. Recording density is achieved in such a carrier (85-100) Gb/dyuym2.
Keywords: nanocomposite, polyacrylonitrile, infrared heating, recording information, the magnetic properties, the carbon matrix
This paper describes a hardware-based and software system parametric estimation of signals. It`s experimental accuracy was achieved measuring the phase difference between the two quasi-harmonic signals at 10 μrad.
Keywords: parametric analysis, technical diagnostics, the phase difference
Measuring the sustainability of the market development of cultivated mushrooms will keep its status through isostatic effects of the complex determinants of development, creating optimal conditions for the movement of his main indicators nevelirovanie their dynamic vibration
Keywords: Market cultivated mushrooms, sustainable development, trend, trend models, the coefficients of variability.
The simulation of two-dimensional spherical crystals consisting of a large number of particles is carried out. These shells were analyzed based on their geometric structure and energy distribution. Various types of defects formed in a state of equilibrium is considered. Being shown the ambiguity of the existing method of their interpretation. A new way of describing such defects in the close-packed two-dimensional crystals with different topology is suggested.
Keywords: topological defects, two-dimensional materials, spherical crystals, topological charge
In the article the features of the visualization for the impact on consumer’s behavior are discussed. There is described an experiment conducted by the authors to assess the impact of neuromarketing methods on customers.
Keywords: neuromarketing, visualization, experiment, the impact on the consumer
In the present work we report on the study of local atomic and electronic structure of gold nanoparticles funnctionalised by thiol and amine containing long-chain ligands. The study of nanoscale atomic structure is performed by means of X-ray absorption spectroscopy (XANES: X-ray Absorption Near-Edge Structure) and computer simulation. In consequence of the experimantally obtained data analysis and computer simulation it was obtained that strong bonding takes place when 11-mercaptoundecanoic acid is bound to the gold nanoparticles surface, forming a chemical bond Au-S 0.25 nm in length. Weaker bonding is observed when forming bond between dodecylamine and gold nanoparticles surface atom resulting in Au-N bond 0.23 nm in length. Supplementary XANES spectra analysis by means of density functional theory reveals the nature of formation of the investigated nanoscale structure.
Keywords: nanoscale structure of matter, X-ray absorption spectroscopy, XANES, density functional theory, nanoparticles functionalisation
We consider a one-step part (B, S) - a market with an infinite number of states. The first part of the article deals with modeling of random behavior of an infinite number of aggressive buyers of the shares in the financial market. There will be described one way to exit the buyers of shares on the market, the gap between the announcement of the share price. In the second part of the article presents the procedure hedge payment obligation (bp), which uses interpolation of incomplete full-arbitrage market economies (Haar interpolation method).
Keywords: Stochastic basis, financial market, martingale measure,the weakened property of the universal Haar uniqueness, self-financing portfolios, capital of portfolio, contingent claim.
The paper studies the possibility of quantitative processing of the GPR data for determining the dielectric permittivity and conductivity of a medium (soil samples). Experimental studies are made using radargrams of soil samples with specified values of moisture and conductivity. New methods of quantitative processing of radargrams are proposed in this work to determine the dielectric permittivity and conductivity of soils. The methods were successfully tested on various sections of Russian railways net.
Keywords: layered road profiling, GPR, soil moisture, soil layers profiling, soil conductivity
This work deals with the study of atomic and electronic structure of kaolinite samples (Glukhovtsy deposit) and montmorillonite (Millerovsky deposit) by density functional theory. The applicability of existing exchange-correlation potential in the local density approximation (LDA) and the generalized gradient approximation (GGA) is analised for an adequate description of the physical properties of layered aluminosilicate. An experimental and theoretical study of the IR spectra of minerals, as well as the identification of the most intense absorption bands, performed in the approximation of DFT using the exchange-correlation potential PW91. The analysis of the band structure of these minerals, which showed that these compounds are direct-gap insulators.
Keywords: DFT, clay, clay minerals, phyllosilicates, atomic and electronic structure, crystalline systems, IR spectrum band strukutra, the electron density
Calcating-experimental method shows that on the basis of cement and fine-grounded mineral powder, complex binding materials can be obtained, providing high strength of obtained stones.
Keywords: cement, mineral powder, components, optimization, strength
This work deals with the integrated study of the composition and structural characteristics of the rock-forming minerals in Millerovsky bentonite clay. The qualitative and quantitative analysis of the clay samples is made by X-ray diffraction , X-ray photoelectron spectroscopy and thermal analysis . The morphological and microstructural features of minerals are investigated by scanning electron microscopy. The application of the method of direct theoretical calculation of the diffraction patterns is showm to determine the crystal-chemical parameters of the studied minerals. The results are aimed at explaining a number of physical and chemical properties of layered aluminosilicate.
Keywords: clays, clay minerals, layered silicates, x-ray diffraction, crystalline systems
Tendencies of technological improvement of electronic chips led to reduction of their sizes, weight, development of functionality and decrease in power consumption. It allows us to discuss questions of developing renewable micro power sources which can provide power supply of autonomous microelectronic and micro circuitry systems for charge indication, paying attention to snow transfer, etc.
The purpose of the paper is researching a profile of electrostatic field potential in the mountain district which was estimated as a possible use as a renewable micro power source.
It is found out that on windward sides of snow relieves the potential of electrostatic field exceeds three times to a similar indicator for lee sides and is 80 V. The potential is 3,5kV on polymeric surfaces (Nylon, teflon).
Keywords: snow storming electricity, electrization, potential of electrostatic field, charge, the salting, the loaded particles of snow, innovation electronics, micro circuitry, renewable micro power sources.
This article deals with the unification of the elements of wood as on the principle of similarity with the material counterpart. Also estimated the economic benefits of the technical parameters of Glulam. As a result of optimizing the size of these elements. Unification is held on the main criterion of similarity bearing members with the solution graphically. Resulting in optimal size sections are then calculated the opportunity cost of production.
Keywords: unification, glued wooden structures
The coloration centres (CC) in crystals of rear earth gallium garnets (REGG): Gd3Ga5O12 (GGG), Gd3Sc1,6Ga3,4O12 (GSGG) и Nd3Ga5O12 (NGG) obtained by Chohraljskiy method, were investigated by methods of optical spectroscopy and spectral analysis in the wavelength range of 0,2-0,87 microns. In the case of keeping the samples under dark conditions, unstable CC were formed in the crystals of GGG and GSGG. The absorption maxima are at λmax1 = 0,243 m and λmax2 = 0,275 m at concentration of N ~ 1018 cm-3. It is suggested that the observed enlightenment is caused by the recharging of growth defects and occurring the energy levels in the band gap of garnets. It appears that these CC correspond to centres of O- holes, originated from gallium vacancies V3-Ga 3+ in tetrahedral and octahedral nots which form near clusters of [V3-Ga 3+ - V2+O2- ]
Keywords: color centers, rare earth gallium garnets, kristylly, Czochralski method, the crystal lattice
Results of the theoretical analysis and applied development of the system of communications and sale of production and services of a restaurant network with use of modern IT technologies are given. Results of modeling and design of the multipurpose website which allows to expand production and economic capabilities of a restaurant network are described. SWOT analysis is executed and the main results of design of the multipurpose website and its integration into a control system and business processes of a network of restaurants are briefly presented. Work is performed with financial support of the Ministry of Education and Science of the Russian Federation within the Federal target program "Researches and Development in the Priority Directions of Development of a Scientific and Technological Complex of Russia for 2007 - 2013".
Keywords: communications, organization of advance and sale of production and services, IT technologies, models, modeling, multipurpose website, network of restaurants, organization and management of restaurant, instrument complex