The process of 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxyl/I2 mediated oxidation of 5-hydroxylmethylfurfural in a twophase system consisting of a methylene chloride and aqueous solution containing sodium hydrogen carbonate was investigated. It was shown that the introduction into the reaction system collidine provides selective oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran (yield 99% at a selectivity of 100%).The optimal composition of the system and the optimal conditions of synthesis were determined. A mechanism of promoting the oxidation of the OH- group of 5-hydroxymethylfurfural and protecting the further oxidation of 2,5-diformylfuran by collidine was proposed.
Keywords: 5-hydroxymethylfurfural, 2,5-diformylfuran, nitroxyl radical, collidine
In this paper we propose basic geometric, mass and electrical parameters of the element for collection of static electricity from the surface of the textile. This element is a reversible electrochemical charge storage system based on nanostructured nickel oxide and carbon cloth. Element has a planar structure, it is flexible, lightweight, safety and ergonomic. Proposed element can be used as a power source for the Microsystems technique in "smart clothes".
Keywords: "smart clothes", microsystems technique, static electricity, supercapacitor, composite material NiO/C